1999年6月24日 · Strongly Entangled Triplet Acyl–Alkyl Radical Pairs in Crystals of Photostable Diphenylmethyl Adamantyl Ketones. Journal of the American Chemical Society 2021 , 143 …

2013年8月14日 · If we keep one variable constant and vary the other variable, we can analyze the influence of structure on free radical stability. Here we’re going to keep H as the variable which …

Visible light photoredox catalysis has enabled easy access to acyl radicals under mild reaction conditions. Reactive acyl radicals, generated from various acyl precursors such as aldehydes, …

The available methods for the generation of acyl radicals and their reactions in solutions are reviewed. The effect of stabilising and polar factors on the reactivity of acyl radicals and the …

Acyl radicals are significant synthetic active species in organic synthesis. However, their generation via green and compatible methods remains challenging. Herein, we report an …

Radical-mediated functionalization of alkenes has been emerging as an elegant and straightforward protocol to increase molecule complexity. Moreover, the abstraction of a …

Abstract Visible-light photoredox catalysis enables easy access to acyl radicals under mild reaction conditions. Reactive acyl radicals, generat-ed from various acyl precursors such as …

2021年2月11日 · Benefited from the redox reaction of large population of radical sites and the excellent stability of reactant R · and oxidation and reduction products R + and R −, …

Acyl radicals, R-CO, are one of the basic classes of carbon free radicals. Their structure confers peculiar chem/cal and physical properties compared with the other simple carbon free radicals. …

In order to evaluate the suitability of acyl radical annelation for the preparation of 6-membered cycVi ketones, we repeated the reaction of citronelloyl cHloride 11 with TBTH/AIBN, and …